Who discovered sulfur. Physical and chemical properties of sulfur. Common signs and differences chalcogen.


DEFINITION

Sulfur   - the sixteenth element of the Periodic table. Designation - S from the Latin "sulfur". Located in the third period, VIA group. Refers to non-metals. The core charge is 16.

Sulfur is found in nature both in the free state (native sulfur) and in various compounds. Sulfur compounds with various metals are very common. Many of them are valuable ores (for example, lead brilliance PbS, zinc blende ZnS, copper brilliance Cu 2 S) and serve as a source of non-ferrous metals.

It is widely distributed in nature, in the free state or in combination. In its free state it mixes with gypsum and pumice in volcanic areas in Iceland, Sicily, Mexico and Japan. Free sulfur can be formed by the natural decay of pyrite precipitated by hot sulfur waters, in which hydrogen sulfide has been oxidized in the atmosphere.

When ordinary sulfur is melted, it forms a straw liquid, which darkens when heated and then boils. When molten sulfur cools slowly, its physical properties change depending on temperature, pressure, and precipitation regime. Thus, sulfur exists in various forms, called allotropic varieties, which consist of liquids.

Of the sulfur compounds in nature, sulfates are also common, mainly calcium and magnesium. Finally, sulfur compounds are found in plants and animals.

Atomic and molecular weight of sulfur

Relative molecular weight of substance (M r)   is a number indicating how many times the mass of a given molecule is greater than 1/12 the mass of a carbon atom, and relative atomic mass of an element   (A r) - how many times the average mass of atoms of a chemical element is greater than 1/12 of the mass of a carbon atom.

It is moderately soluble in alcohol and ether and moderately soluble in oil. The temperature at which rhombic and monoclinic sulfur are in equilibrium, i.e. 94, 5 ° C, is the transition temperature. Sulfur is chemically similar to oxygen and can be substituted in many combinations, but sulfur is less electronic.

In Sicily, sulphurous rocks are piled on the ground and burned. The resulting liquid sulfur is poured into a series of wooden forms in which it solidifies. Then it can be purified by distillation. Sulfur is mainly used in the production of compounds such as sulfuric acid, sulphides, sulphates and sulfur dioxide. Sulfur is widely used in sulfamide-based preparations and in many dermatological ointments. Sulfur is also used in the manufacture of matches, vulcanized rubber, dyes and gunpowder. In a finely divided state and often mixed with lime, it is used as a fungicide for plants.

The values ​​of atomic and molecular mass of sulfur coincide; they are 32.059.

Allotropy and allotropic modifications of sulfur

Sulfur exists in the form of two allotropic modifications - rhombic and monoclinic.

At normal pressures, sulfur forms fragile yellow crystals, melting at 112.8 o C; density is 2.07 g / cm 3. It is insoluble in water, but rather well soluble in carbon disulfide, benzene and some other liquids. When these liquids evaporate, sulfur is released from the solution in the form of yellow crystals of the rhombic system, having the form of octahedra, in which usually some of the corners or edges are cut off (Fig. 1). This modification of sulfur is called rhombic.

Potassium and ammonium sulfates are used as fertilizers, and together with various inert mineral charges, sulfur forms a special cement used to anchor metal objects, such as fences and chains made of stone. Sulfuric acid is one of the most important industrial chemicals, since it is used not only for the synthesis of sulfur-containing molecules, but also for the production of many other compounds.

At a time when everyone talks about microelements, sulfur is often forgotten. It is important to recall some common facts and evidence of sulfur. Fumaroles that are mainly deposited in volcanic zones, precipitating sulfur crystals, are very fragrant, highly flammable, therefore its use in the production of gunpowder, sulfur is demographic culturally, and yet we find that sulfur is of paramount importance to life.

Fig. 1. Allotropic modifications of sulfur.

Crystals of a different form are obtained if the molten sulfur is slowly cooled and, when it partially solidifies, the liquid which has not yet had time to solidify is drained. Under these conditions, the vessel walls are covered from within by long dark yellow needle-like crystals of the monoclinic system. This modification of sulfur is called monoclinic. It has a density of 1.96 g / cm 3, melts at 119.3 o С and is stable only at temperatures above 96 o C.

Some very original chemical communities. Sulfur is a simple chemical non-metallic, acidic, light yellow. After its crystallization, it has an aspect. Glossy and translucent matte and opaque. . Very loose, it has several melting points with amazing features.

Sulfur reacts with most other elements to form sulfates or sulphides. It is mixed with carbon hydrocarbons and natural gas. Sulfur due to its acidic nature is ideal for the production of various acids: sulfuric acid, sulfuric acid, widely used in all industries.

Sulfur isotopes

It is known that sulfur in nature can be in the form of four stable isotopes 32 S, 33 S, 34 S and 36 S. Their mass numbers are 32, 33, 34 and 36, respectively. The nucleus of the sulfur isotope 32 S contains sixteen protons and sixteen neutrons, and the isotopes 33 S, 34 S and 36 S contain the same number of protons, seventeen, eighteen and twenty neutrons, respectively.

Sulfur at the beginnings of life. Sulfur is vital, it, besides the origin of life, on the other hand, its derivatives can be very toxic or even mortal. Sulfur - acid, life too. Present in all proteins of living organisms, thanks to sulfur in albumin, the water of our body remains structured. Without sulfur, we would be only a meadow.

There is more sulfur in the blood than iron, and when you know very specific chemical relationships between these two elements, it would be interesting to use sulfur in case of anemia or hemochromatosis. The effect of a gray stone massage on the liver should quickly resolve this disorder around the iron.

There are artificial isotopes of sulfur with mass numbers from 26 to 49, among which the most stable is 35 S with a half-life of 87 days.

Sulfur ions

At the outer energy level of the sulfur atom there are six electrons that are valence:

1s 2 2s 2 2p 6 3s 2 3p 4.

As a result of chemical interaction, sulfur can lose its valence electrons, i.e. be their donor, and turn into positively charged ions or accept electrons of another atom, i.e. be their acceptor, and turn into negatively charged ions:

Sulfur, regulator of the skin and lungs. Due to its acidic nature, sulfur contained in the skin provides the boundary between the internal environment of the body and the external environment, which can be subjected to various types of attacks. We find sulfur in abundance in keratin, the main protective protein of the skin.

Similarly, sulfur will be "protective" from the lungs. However, this is not about sulfur inhalation. A simple daily massage of the chest will relieve many chronic respiratory problems. Moreover, people with chronic epidermal or pulmonary disorders do not regularly go to sanatorium-resort treatment, where they have very sulfuric water treatment to get rid of their sufferings.

S 0 -6e → S 6+;

S 0 -4e → S 4+;

S 0 -4e → S 2+;

S o + 2e → S 2-.

Sulfur molecule and atom

A sulfur molecule is monoatomic - S. Let us give some properties that characterize an atom and a sulfur molecule:

Examples of problem solving

EXAMPLE 1

Sulfur (from lat. sērum   “Serum”) is a mineral of the class of native elements, non-metal. Latin name is associated with indo-European   the root of the swelp is "burn." Chemical formula: S.

To improve your health, we have developed this compact sulfur stone, which allows you to get the massage as close as possible to all your aches and pains. After a few minutes of massage, you are aware of the real relief, and during the re-massage sessions there will be a real improvement. To order your sulfur stone, click here.

One solid body, not metallic, of lemon yellow color. Sulfur exists in two crystalline forms. The resulting cold by evaporation of its solutions is represented in the octahedra of the orthorhombic system, the density is 2. 06; by melting molten sulfur, it crystallizes in the needles of the monoclinic density system 1.

Sulfur, unlike other native elements, has a molecular lattice, which determines its low hardness (1.5-2.5), lack of cleavage, brittleness, uneven fracture and the resulting heavy splash; only on the surface of the crystals there is a glassy sheen. The specific gravity is 2.07 g / cm 3. It has poor electrical conductivity, low thermal conductivity, low melting point (112.8 ° C) and ignition (248 ° C). Easily ignites from a match and burns with a blue flame; this produces sulfur dioxide with a sharp, suffocating odor. The color of native sulfur is light yellow, straw yellow, honey yellow, greenish; Sulfur containing organic matter, acquire a brown, gray, black color. Volcanic sulfur is bright yellow, orange, greenish. Mostly usually with a yellowish tinge. There is a mineral in the form of solid dense, drip, earthy, powdered masses; there are also growing crystals, bumps, scurfs, crusts, inclusions and pseudomorphs of organic residues. Rhombic syngony.

Soft sulfur is a brown, pasty and elastic solid obtained by pouring molten sulfur into cold water at its boiling point. Sulfur is in a natural state near ancient volcanoes, which is 0.06% of the lithosphere. Most often it is combined with metals, and sulphides of iron, copper, lead, zinc are important minerals of these metals. Purified, it is used in the production of black powder and fireworks.

It is also used for making matches, curing rubber and making ebonite. Sulfur is used internally as a mild laxative and in external applications for its antiparasitic, keratolytic and antiseborrheic properties. An element with a sulphurous reputation?

Features: characteristic of native sulfur: non-metallic luster and the fact that it ignites from a match and burns, emitting sulfur dioxide, which has a sharp, suffocating smell. The most characteristic color for native sulfur is light yellow.

Variety:

Vulcanite   (selenisty sulfur). Orange-red, red-brown color. The origin is volcanic.

Sulfur is in the standard state of a yellow solid, odorless, tasteless, insoluble in water, with poor mechanical properties, a very poor conductor and diamagnetic. Sulfur exists in molecular form. It is in a state of powder: a flower of sulfur, which is obtained by sublimation.

Molded block: sulfur in the barrel; as well as in aggregate. It is possible to obtain colloidal sulfur or sulfuric milk, as well as plastic sulfur and various amorphous forms of sulfur by quenching molten sulfur. Sulfur has a wide range of allotropic forms.

Monoclinic sulfur Crystal sulfur Crystal sulfur Selenium sulfur - volcanic

Sulfur Chemical Properties

Lights up from a match and burns with a blue flame, this produces a sulfur dioxide gas that has a sharp, suffocating smell. It melts easily (melting point 112.8 ° C). Flash point 248 ° C. Sulfur is dissolved in carbon disulfide.

The place of sulfur in the periodic classification is the electronic configuration. Its atomic number is 16; It is classified as non-metal. Column 16 Representation: Oxygen Family. Sulfur reacts quite easily with many elements of the periodic table, both with metals and non-metals.

Like oxygen, sulfur has an oxidation state of -2 and gives sulfides. Since sulfur is less electronegative than oxygen, it also has oxidation states 4, 6 with more electronegative elements. Other oxidation states are possible: for example, 1, but also 2, 2 and 3 in the case of tetrathionate ion 3, 5, 7. Frost diagram. However, many of these compounds can be considered to be formed by combinations of sulfur atoms in oxidation states of 4 or 6 and sulfur atoms in the 0, -2, or -1 oxidation stages.

Sulfur origin

Native sulfur of natural and volcanic origin is encountered. Sulfur bacteria live in water basins, enriched with hydrogen sulfide due to the decomposition of organic residues - at the bottom of swamps, estuaries, small marine bays. The estuaries of the Black Sea and Sivash Bay are examples of such bodies of water. The sulfur concentration of volcanic origin is confined to volcanic vents and to the voids of volcanic rocks. During volcanic eruptions, various sulfur compounds (H 2 S, SO 2) are released, which are oxidized under surface conditions, which leads to its restoration; in addition, sulfur is sublimated directly from the vapor.

For example: a thiosulfate ion, in which one of the sulfate oxygen atoms is replaced by a sulfur atom, has two sulfur atoms, the oxidation numbers of which are different - "4, 0" or 6, -2 depending on how the electrons are counted. The property of concatenation of sulfur makes it difficult to determine the amount of oxidation of the sulfur atom in molecules and formed ions.

Sulfur has many compounds where the byte rule no longer applies. Sulfur, which is more voluminous than oxygen, can accommodate more neighbors. Atomic properties, isotopes. There are four natural isotopes, all stable. Several artificial sulfur isotopes are known.

Sometimes in volcanic processes sulfur is poured out in liquid form. This happens when sulfur, previously deposited on the walls of craters, melts with increasing temperature. Sulfur is also deposited from hot aqueous solutions as a result of the decomposition of hydrogen sulfide and sulfur compounds released during one of the later phases of volcanic activity. These phenomena are now observed near the vents of geysers of Yellowstone Park (USA) and Iceland. It is found together with gypsum, anhydrite, limestone, dolomite, rock and potassium salts, clays, bituminous deposits (oil, ozocerite, asphalt) and pyrite. It is also found on the crater walls of volcanoes, in cracks of lavas and tuffs, surrounding volcano vents, both active and extinct, near sulfur mineral springs.

Appearance and abundance and achievement. Sulfur is in its natural state, near volcanoes or in natural sediments in the open air or underground. But also in the form of sulphides and sulphates of metals: cinnabar, galena, opium, barite, gypsum, etc. Removal of natural gas and oil desulfurization.

Exploitation of sulfur deposits in a natural state. The most important use of sulfur is the production of sulfuric acid. Sulfur is a fungicide used for viticulture and horticulture. Vulcanization of natural rubber always uses a significant amount of sulfur.

Satellites. Among the sedimentary rocks are gypsum, anhydrite, calcite, dolomite, siderite, rock salt, sylvite, carnallite, opal, chalcedony, bitumen (asphalt, oil, ozocerite). In the deposits resulting from the oxidation of sulphides, mainly pyrite. Among the products of volcanic sublimation: gypsum, realgar, orpiment.

Application

Widely used in chemical industry. Three quarters of sulfur production goes to sulfuric acid. It is also used to combat agricultural pests, in addition, in the paper, rubber industry (vulcanization of rubber), in the manufacture of gunpowder, matches, in pharmaceuticals, glass, food industry.

Carbon disulfide is produced by the interaction of sulfur with methane. We also mention the sulfur-sodium electrochemical cells, the storage capacity of which is the main event today. Basic sulfur compounds and some of their uses. Sulphuric acid: neutralization, leaching, production of hydrofluoric acid, production of titanium dioxide, lead batteries, metal etching, dehydration of alcohols, paraffin paper, etc.

Ferrous sulfate or green vitriol. Calcium hydrogen sulfite. Organic compounds containing sulfur: thiols, thioethers, and the like; They are widely used in the pharmaceutical and agrochemical industry. The element is gray and alive. Sulfur is one of the indispensable elements in life.

Sulfur deposits

In the territory of Eurasia, all industrial deposits of native sulfur of surface origin. Some of them are located in Turkmenistan, in the Volga region, and others. Breeds containing sulfur are stretched along the left bank of the Volga from Samara by a strip having a width of several kilometers to Kazan. Probably, sulfur was formed in the lagoons in the Permian period as a result of biochemical processes. Sulfur deposits are located in Razdol (Lviv region, Carpathian region), Yavorivsk (Ukraine) and in the Ural-Emba region. In the Urals (Chelyabinsk region) there is sulfur formed as a result of pyrite oxidation. Sulfur of volcanic origin is available in Kamchatka and the Kuril Islands. The main reserves are in Iraq, the United States (Louisiana and Utah), Mexico, Chile, Japan and Italy (Sicily).

It is found in two essential amino acids: cysteine ​​and methionine, but also in homocysteine ​​and taurine. Enzymes owe their configuration to "disulfide" bridges, which lead to protein bending on themselves. When the bread “rises”, it is obliged to them to “disulfide” bridges of the cysteine-cystine pair, also responsible for the undulation of the hair.

They are still found in the oceans near volcanic faults. The history of the discovery of the element sulfur. Sulfur is one of the nine known elements from antiquity. This is cited in the Old Testament. It is used for cosmetic, therapeutic purposes. Sulfur is also mentioned in Homer's Odyssey upon returning to Ithaca; Sulfur had the ability to remove pests!